Bis[4-(1-iminoethyl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ2O,N4]copper(II)
نویسندگان
چکیده
منابع مشابه
4-(3-Methyl-5-phenyl-1H-pyrazol-1-yl)benzenesulfonamide
With respect to the planar five-membered ring of the title compound, C(16)H(15)N(3)O(2)S, the phenyl ring is aligned at 47.0 (1)° and the phenyl-ene ring at 37.6 (1)°. The amino group has the N atom in a pyramidal geometry; the group is a hydrogen-bond donor to the sulfonyl O atom of one mol-ecule and to the pyrazole N atom of another mol-ecule, resulting in the formation of a layer parallel to...
متن کاملTris(5-methyl-3-phenyl-1H-pyrazol-1-yl)methane
The first crystal structure of a second-generation tris-(pyrazol-yl)methane, namely the title compound, C(31)H(28)N(6), is reported. The mol-ecule exhibits a helical conformation with an average twist of 35.1°. In addition, there are C-H⋯π inter-actions of 3.202 (2) Å between the pyrazole C-H group and neighbouring phenyl groups.
متن کاملBis[4-(1-iminoethyl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ2 O,N 4]copper(II)
In the title complex, [Cu(C(12)H(12)N(3)O)(2)], the Cu(II) ion is tetra-coordinated by two N atoms and two O atoms from two bis-chelating 4-(1-imino-eth-yl)-3-methyl-1-phenyl-1H-pyrazol-5-olate ligands in a square-planar geometry. The two N atoms and two O atoms around the Cu(II) atom are trans to each other, as the Cu(II) atom lies on an inversion centre. The six-membered ring composed of the ...
متن کامل4-[(3-Hydroxyanilino)(phenyl)methylidene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-one
In the title compound, C(23)H(19)N(3)O(2), the dihedral angles formed by the pyrazolone ring with the three benzene rings are 30.91 (6), 60.96 (4) and 57.01 (4)°. The ligand is in the enamine-keto form and its structure is stabilized by an intra-molecular N-H⋯O hydrogen bond. In the crystal, O-H⋯N hydrogen bonds link mol-ecules into chains parallel to [01-1].
متن کامل(±)-3-(5-Amino-3-methyl-1-phenyl-1H-pyrazol-4-yl)-2-benzofuran-1(3H)-one
In the title compound, C18H15N3O2, the benzo-furan ring system is essentially planar, the rings making a dihedral angle of 0.57 (9)°. The phenyl, furan and benzene rings subtend dihedral angles of 47.07 (10), 85.76 (7) and 86.04 (7)°, respectively, with the pyrazole ring. In the crystal, mol-ecules are linked by weak N-H⋯N, N-H⋯O and C-H⋯O inter-actions, generating edge-fused R 4 (4)(20), and R...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811030753